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How Batteries Work: Voltage, Capacity and Energy

Every battery label carries the same three ideas: voltage, capacity and energy. Once you understand how they fit together, you can read any battery label, from a phone power bank to a caravan battery or a home solar battery, and compare them properly.

1. What a battery does

A battery stores energy as chemical energy and releases it as electricity when a circuit is connected. Inside, it's made of one or more cells. Each cell has a positive and a negative side and makes a voltage set by its chemistry.

Charging pushes energy back in. Discharging lets it flow out through whatever is connected.

2. Voltage: the push

Voltage is the electrical "pressure" that pushes current around a circuit. In the water hose picture from Volts, Amps, Watts and Ohms, it's the water pressure.

The Series vs Parallel lesson explains how cells and batteries combine.

3. Capacity: amp-hours (Ah)

Capacity tells you how much charge a battery holds, in amp-hours (Ah). In theory, a 100Ah battery could supply:

Real batteries deliver a bit less at high currents, and less in the cold, so treat this as a guide.

Small batteries use milliamp-hours (mAh): 1,000mAh = 1Ah.

4. Energy: watt-hours (Wh)

Energy is what actually runs your appliances. It's measured in watt-hours (Wh), or kilowatt-hours (kWh) for big batteries: 1kWh = 1,000Wh.

Watt-hours = nominal voltage × amp-hours

The mAh, Ah and Wh Converter does these sums.

Volts times amp-hours equals watt-hours: 12.8V times 100Ah is 1,280Wh. A 25.6V 100Ah battery holds 2,560Wh, so amp-hours only compare batteries of the same voltage. Below, watts compared with watt-hours, and 1,024Wh usable running a 40W load for about 25.6 hours.
Watt-hours use the nominal voltage. Example figures from the lesson.

5. Why amp-hours alone can mislead

Amp-hours only compare batteries of the same voltage. Two batteries can have the same Ah but very different energy.

Worked example: two batteries, both labelled 100Ah.

Same amp-hours, but Battery B holds twice the energy.

And the other way round:

Different amp-hours, same energy.

When batteries have different voltages, compare watt-hours, not amp-hours.

6. Usable capacity: not all of it is for you

A battery's rated capacity isn't always all usable.

Worked example: two 12V 100Ah batteries.

Same amp-hour rating, but the lithium battery gives you about 1.7 times the usable energy in this example. The LiFePO4 vs AGM lesson goes into the differences.

7. Turning energy into running time

Once you know the usable energy, you can estimate how long something will run:

Hours ≈ usable watt-hours ÷ watts drawn

Worked example: the LiFePO4 battery above, with 1,024Wh usable, running a 40W load.

If the load runs through an inverter, the battery supplies more than the load uses, because the inverter loses some energy. Allow for the inverter's efficiency.

8. Other things that change real capacity

9. Common beginner mistakes

10. Safety boundaries

  • Batteries store a lot of energy, and even small ones can deliver a large current into a short circuit. Keep metal tools, jewellery and loose wires away from the terminals.
  • Never charge or use a battery that is swollen, leaking, hot or damaged. If one is smoking or on fire, get away and call 000.
  • Use only a charger that suits the battery's chemistry and voltage.
  • In Australia, work on 240V AC mains wiring must be carried out by a licensed electrician.

11. The main lesson

Voltage is the push. Amp-hours are the charge. Watt-hours are the energy, and they're the fair way to compare batteries. Then check how much of it you can actually use.

Continue learning

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Technical note: This is general educational information, not a substitute for a design calculation, manufacturer instructions or applicable Australian standards.

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